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Research program Foundation Emulsion Polymerization Approved during the SEP meeting November 2009 1. Process control in (mini-)emulsion (co/ter)polymerization - Emulsion co- and terpolymerization; prediction, control and parameters, including partitioning and nucleation - Combinatorial latex synthesis procedures and high-throughput screening of polymeric materials - On-line monitoring in (mini-)emulsion (co)polymerization - Propagation in the aqueous phase and entry in (mini-)emulsion copolymerization 2. Special particle morphologies - Hybrid latices containing inorganic particles, prevention of secondary nucleation - Interactions between latex particles and inorganic particles - Control of latex morphology (including non-spherical latices and hollow particles) - Preparative Pulsed Initiation Polymerization and preparation of small latex particles - Characterization of high MW polymers through electron microscopy 3. Functionalized latex particles for coating applications - Block copolymers as surfactants - Incorporation of a-olefins and hydrophobic monomers in latex particles - Antimicrobial latex particles (antimicrobial PU coatings) 4. CCT and CRP in (mini-)emulsion - Several mechanistic aspects of CCT and CRP in (mini-)emulsion. (Applications) - CRP in aqueous solution of ionic monomers 5. Scaling-up of (mini-)emulsion polymerization, Process intensification - Process aspects of (mini-)emulsion polymerization. More efficient methods of manufacture. Continuous operations 6. Artificial latices - Artificial latices and emulsification 7. Film formation - Film formation 8. Coagulation phenomena - Product innovation (colloidal stabilization mechanisms). Mechanism of microcoagulation 9. Reduction of residual monomer - Approaches to reduce residual monomer 10. Sustainable latex technology - Sustainable product- and process technology focusing on polymer dispersions - Monomers and surfactants from renewable (i.e. natural) sources
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